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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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生物 大学生・専門学校生・社会人

至急お願いいたします🚨 生物の質問です。 ミトコンドリアの経路についての説明だと思うのですが、電子オーバーフローモデルと電子分布モデルの違いを教えていただきたいです。 また、どういう仕組みなのか、何故このように電子が流れるのかも教えていただきたいです。 UQ poolはユ... 続きを読む

(A) Electron overflow model (considered out-of-date) Alt UQ pool Alternative oxidase inactive. Alt No alternative pathway activity Cytochrome pathway unsaturated Cyt (B) Electron distribution model (reflects current thinking) UQ pool Cyt Alternative pathway active Cytochrome pathway saturated Alt Alternative oxidase active Alt UQ pool Cyt Cyt Figure 14.33 Two models for regulation of electron flow through the alternative oxidase. (A) In the electron overflow model, no appreciable electron transfer through the alternative pathway takes place until electron flow through the cytochrome pathway is at or near satu- ration. This could result from the effects of respirato- ry control, if the rate of mitochondrial ATP produc- tion exceeds its rate of utilization in the cytosol, or from some externally imposed stress, such as low temperature. Under such circumstances, the UQ pool becomes sufficiently reduced to allow electrons to flow through the alternative oxidase, the latter re- quiring that the UQ pool be 40% to 60% reduced to attain significant activity. (B) In the electron distribu- tion model, the alternative and cytochrome path- ways both show significant activity at low levels of UQ pool reduction, and electrons are distributed be- tween the two pathways on the basis of the relative activities of each pathway. The activity of the alter- native oxidase under these circumstances is thought to be regulated by the action of a-keto acids and by reduction/oxidation of the intermolecular disulfide bond, as well as by additional regulatory mecha- nisms not yet characterized.

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英語 高校生

考えても分かりません。解答お願いします

20 Unit 1 - History - Gutenberg is famous for inventing printing, but he didn't really invent it. He invented a better way of printing. [2] For hundreds of years people used blocks of wood* to print. They used a knife to cut words backward in the block of wood. Then they covered the block with ink and pressed it onto paper. When they pulled the paper from the inky blocks, the words appeared on the 金属 5 paper in the right direction. In Korea and China, people printed with metal type* instead of 右向き wood. (2)Either way, printing was difficult and very slow. It took several years to make one copy of a book. [3] Books were very expensive and rare. Only ( 3a ) people could buy them, and ( 3b ) 10 people could not read. But, as ( 3c -) people learned to read, books became more popular. So people wanted to find a quicker, better and less expensive way to print books. One of these people was Johannes Gutenberg. opsugas.l Y tinU 9003 iinil 4 Gutenberg was born in Mainz, Germany, around 1400. He was good at working with metal, but probably had no idea how people printed in China. His idea was to make a piece Clarey operan 15 of metal type for each letter of the alphabet and use the letters (4)over and over. (5)He could put the type together to make words and arrange words to make pages. With ink on the type, he could press paper on them to print a page. A "printing press" machine could make hundreds of copies of a single page quickly. After that page, he could rearrange the same letters to make other words and print other pages. LISSH Si nou 5 It took Gutenberg a long time to make the type for each letter of the alphabet. When he finished the type, he didn't have enough money to make the printing press. He borrowed money from a man named Johann Fust. After many years, Gutenberg's printing press was Legione ready. Gutenberg printed his first book, the Bible, around 1455. 6 There are only twenty-one complete copies of the original Bible. They are some of the 25 most expensive books in the world. In 1987, part of a Gutenberg Bible sold for $5.3 million. 7 Today people remember Johannes Gutenberg. The city of Mainz has a statue of him and a museum. His original printing press is in the museum. (6)They print several pages a day to show that it is in good condition. earoviaU 012mu 394 words/#IN block of wood: type: vrigsypola 01 sind 7 an Oupside down & 下線部 (6) を日本 7. 本文の内容に合わ Many people & Gutenberg g Gutenberg Olt was a long Though Gu cost a lot of Hannes Rotest

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英語 高校生

仮定法の範囲です 6〜21、20、24〜26の答え教えてください! 解いたのであってるかみてほしいです。不正解の場合正しい回答もしりたいです🙇‍♂️

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