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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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英語 高校生

赤線を引いているところがよくわからないのですが、まず、 1、母と議論するのは難しかったとありますが、何についての議論か 2、最後の分の「彼女は首に巻いた〜合図であった」は何を意味しているのでしょうか できれば要約をお願いしたいです🙇

14 第6問 次の文章を読み、下の問いに答えよ。 標準解答時間 9分 depressed. It was not the exam that made her feel that Christine came out of her last examination, feeling way, but the fact that it was the last one; it meant the end of the school year. She dropped in at the coffee 5 as usual, then went home early because there didn't 10 seem to be anything else to do. shop "Is that you, dear?" her mother called from the living room. She must have heard the front door close. Christine went in and sat on the sofa. "How was your exam, dear?" her mother asked. "Fine," said Christine flatly. It had been fine; she had passed. She was not a brilliant student, she knew, but she was hard-working. Her professors always wrote things like "A serious attempt" and "Well thought out but 15 perhaps lacking in energy" on her term papers; they gave her Bs, the occasional B*. She was taking Political Science and Economics, and hoped to get a job with the government after she graduated; with her father's connections she had a good chance. 20 "That's nice." Christine felt, bitterly, that her mother had only a vague idea of what an exam was. She was arranging roses in a vase; she had rubber gloves on to protect her hands as she always did when engaged in what she 25 called 'housework.' As far as Christine could tell, her housework consisted of arranging flowers in vases. Sometimes she cooked elegantly, but she thought of it as a hobby. It was hard, anyway, to argue with her mother. She was so easily upset that it was better to avoid 30 arguing with her.

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英語 中学生

3.4枚目が問題文、5枚目が答え、1.2枚目は問題を解くときに必要な文です。 なぜこの答えになるのかがわからないので教えてください。 解くのは大変だと思うので、一問だけでも大丈夫です。

2 次は, 高校1年生の Yusuke が書いた英文です。 これを読んで、 問1~間6に答えなさい。*印 のついている語句には、本文のあとに 〔注〕があります。(34点) My father loves *dinosaurs and *fossils. He (he/them/in/collects/is/that/interested /so) dinosaur toys, small fossils and books about dinosaurs. I heard he tried to find fossils along the river with my grandparents when he was young. When I was younger, my family took me to the science museum every year. My father loved looking at the dinosaur fossils there, and he always explained them to me. So, I got interested in dinosaurs and fossils, too. My father has a restaurant near our house, and he displays some dinosaur teeth fossils in the restaurant. One day, he introduced one of his customers to me. The man, Mr. Shirai, also loved dinosaurs and fossils, and often visited museums all around the world, such as in America, Canada and China. He realized that my father was interested in the same things because of the fossils in the restaurant. They became good friends. One day in September, Mr. Shirai came to my father's restaurant and showed me a fossil. It was a beautiful fish fossil in a brown stone plate. I was surprised to see it, Mr. Shirai A me a lot about the fossil. He traveled to Germany to look for fossils, and he found many fossils there such as fish, animal bones and leaves. The area is very famous for "archaeopteryx fossils. I once saw a picture of the archaeopteryx fossil in a book, so I wanted to go to see the fossil in -4-

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