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自然科學 大學

想問3-9的a跟c

Problems 3-1. Explain the difference between *(a) random and systematic error. (b) constant and proportional error. *(c) absolute and relative error. (d) mean and median. *3-2. Suggest two sources of systematic error and two sources of random error in measuring the length of a 3-m table with a 1-m metal rule. 3-3. Name three types of systematic errors. *3-4. Describe at least three systematic errors that might occur while weighing a solid on an analytical balance. *3-5. Describe at least three ways in which a systematic error might occur while using a pipet to transfer a known volume of liquid. 3-6. Describe how systematic method errors may be detected. *3-7. What kind of systematic errors are detected by varying the sample size? 3-8. A method of analysis yields masses of gold that are low by 0.4 mg. Calculate the percent relative error caused by this result if the mass of gold in the sample is (a) 500 mg. (b) 250 mg. V(c) 125 mg. (d) 60 mg. 3-9. The method described in Problem 3-8 is to be used for the analysis of ores that assay about 1.2% gold. What minimum sample mass should be taken if the relative érror resulting from a 0.4-mg loss is not to exceed *(a) -0.1%? (b) -0.4%? (c) -0.8%? (d) - 1.1%? 3-10. The color change of a chemical indicator requires an overtitration of 0.03 mL. Calculate the error if the total volume of titrant is percent relative (a) 50.00 mL. (c) 25.0 mL. 3-11. A loss of 0.4 mg of Zn occurs in the course of an percent relative analysis for that element. Calculate the error due to this loss if the mass of Zn in the sample is *(b) 10.0 mL. (d) 30.0 mL. 190 (c) 188 (d) 4.52 x 103 4.63 x 103 4.53 x 10 ³ √6 *(a) 30 mg. (b) 100 mg. *(c) 300 mg. (d) 500 mg. 3-12. Find the mean and median of each of the following sets of data. Determine the deviation from the mean for each data point within the sets, and find the mean devi- Vation for each set. Use a spreadsheet if it is convenient. *(a) 0.0110 0.0105 (b) 24.53 0.0104 24.68 24.81 24.77 39.61 862 (f) 850 MA 3-13. Challenge Problem: Richards and W the molar mass of lithium and colle data. 24.73 Experiment 1 2 3 4 5 6 194 447 X 10 7 448 X 107 4.58 X 10 (a) Find the mean molar t workers. (b) Find the median molar ma (c) Assuming that the cam molar mass of lithium is the absolute ertor and of the mean value demi Willard. (d) Find in the chemical ues for the molar mus since 1910, and ag a table or spreadshera 1817 given in the a Richards and Willd. Com mass versus year to la of lithium has chang Suggest possible abruptly about 18 ant de (e) The incredibly deals Richards and W that major changes will occur. Disc calculation in pat (f) What factors ha since 1910? (g) How would you mass? 6See Chapter 2 of Applications of Microsoft Excel in Analytical Chemistry, 4th ed., for information about statistical 7T. W. Richards and H. H. Willard, J. Am. Chem. Soc., 1910, 32, 4, DOI: 10.1021/ja01919a002. built-in statistical functions. "Answers are provided at the end of the book for questions and problems marked with an asterisk The I of ₂ or inc rce of able vas error c often in individu ate resul data in rtainties. dimensio andom e analysts The result

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自然科學 大學

求解答案是否正確

Multiple-choice questions: (70 points) write the letter of statement that is not true: 1. A.B.U The Drude Model: (a) It is a classical approach using concepts from the kinetic theory of gases. (b) A relaxation-time approximation is used where the probability of collision is l/t. (c) No forces act on the electrons in between collisions. (d) It predicts accurately the electronic heat capacity of metals. 2. The Sommerfeld Model: (a) The crystal potential is replaced by an average Coulomb potential. (b) The separation of states is so close that a continuum model can be applied. (c) The electrons are highly localized due to a strong crystal potential. (Q) The energy of the highest occupied state at 0 K is the Fermi energy. 3. Density of states in k-space, N(k): (a) N(k) is determined by the boundary value conditions. (b) For lattices in any dimensions, N(k) is constant in k-space. (C) N(k) depends on the direction and magnitude of k. (d) It is directly proportional to the volume of the crystal. E影響, c 4. The Fermi surface of a metal: (a) is responsible for many of the transport properties of the metal, (b) depends on the nature of the chemical bonds, (c) is always a sphere, (d) can involve mixing of electron orbitals. ✓ 5. The conductivity of a material () increases with the mobility of its carriers, (b) increases with the density of carriers, (C) it is inversely proportional to the energy gap. cogu changes with temperature. 6. BID Plasmons: (a) They are an important characteristic of the Sommerfeld electron gas model. (b) Plasmons occur spontaneously in metals. (c) They are related to charge density oscillations. (d) The Plasmon energy is typically of the order of 10 eV. The Fermi energy Ef in intrinsic semiconductors 8) is usually close to y E, at OK (b) it ACiD. can increase or decrease with temperature depending on the ratio of hole and electron effective masses, (c) it represents the point at which the probability of occupation is 12, even though there may not been any states with that energy, (d) its value relative to the electronic bands must remain unaffected in the presence of defects or interfaces.

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