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化学 高校生

緩衝液のphの求め方教えて下さい。お願いします🙇‍♂️

◆問題 343 発 緩衝液 0.10Lの酢酸水溶液10.0mLに0.10mol/Lの水酸化ナトリウム水溶液 5.0mL を 加えて、緩衝液をつくった。 この溶液のpHを小数第2位まで求めよ。 ただし,酢酸の 電離定数を Ka=2.7×10-5mol/L,log102.7=0.43 とする。 LOW 第章 物質の変化と平衡 考え方 反 解答 ( 緩衝液中でも,酢酸の電離平衡 が成り立つ。混合水溶液中の酢 酸分子と酢酸イオンの濃度を求 め, 電離平衡の量的関係を調べ ればよい。このとき,酢酸イオ ンのモル濃度は,中和で生じた ものと酢酸の電離で生じたもの との合計になる。これらの濃度 を次式へ代入して水素イオン濃 度を求め, pH を算出する。 残った CH3COOH のモル濃度は, 0.10× 10.0 1000 -mol-0.10× 5.0 1000 mol 0.10 x mol (15.0/1000) L また,生じた CH3COONa のモル濃度は, 5.0m 1000 = 0.0333mol/L (S) (g) m0.0 -=0.0333mol/L (15.0/1000) L 混合溶液中の [H+] を x[mol/L] とすると, 平衡状態CH3COOH 1 H+ + CH3COO- はじめ 0.0333 [H+][CH3COO-] 平衡時 0.0333-x 0 x 0.0333+x 0.0333 [mol/L] [mol/L] Ka= ① 340 [CH3COOH] [CH3COOH] [H+]= ② [CH3COO-] xの値は小さいので, 0.0333-x= 0.0333,0.0333+x= 0.0333 とみなすと, ②式から [H+] = Ka となるため, pH=-logio [H+]=-logio (2.7×10-5)=4.57 X 発展例題28 溶解度積 問題 346 347

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英語 高校生

カッコで囲んだとこの英文の1つ目のandからの訳がどうして2枚目のようになるのか教えてください。 2枚目のどんな疑問が重要か〜の次のとこからです

ample practices varied across time and place. The truth is that we about what preliterate societies knew or believed. But they left behind *. evidence of their attention to the movements of the Sun and the phases of the Moon. And we can be sure that whatever questions they asked of the heavens were very different from those that motivate space exploration today. (A) rotic othe In reality, the difference between ancient and modern knowledge systems is more qualitative than quantitative; it is not about how much is known, but about what questions are important and about the acceptable ways of asking and answering those questions. And while we may not easily be able to slip between our modern worldview and those of others, we can nonetheless attempt to do so by asking not what ancient people knew about the world, but what their questions were when they looked at it. If we do this in the case of Mars, examining a few of the earliest known examples from around the world, we can see how sky knowledge was considered important to the functioning of the state whether it was *astrological knowledge in the service of good governance, or knowledge of bloodlines and relationships with the gods and other sky entities, which was used (B) - verdd

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