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化学 大学生・専門学校生・社会人

緊急です、!!!! この反応機構を矢印付きでお願いしたいです、、🥺

21:21 三 46 について | セクション 2.2 NeuroPコアの不斉合成 これ 林ピロリジン触媒存在下での9aの8への有機触媒マイケ ル付加反応とそれに続くアルデヒドの還元は、我々の以 前の報告 [26]と同様に行われ、2段階で89%の収率でアル コール7aが3:1のシン/アンチジアステレオマー混合物と して得られ、シン-7aで86%のee、 アンチ-7aで90%のee であった(図3)。 続いて、 キャンディらの条件下での 酸化Nef反応により、 87%という非常に良好な収率と16:1 のジアステレオマー比で二置換ラクトン11が得られ、 はDBU触媒による熱力学的平衡によってさらに濃縮され た。ラクトンをDIBAL-Hで還元してラクトール6aを得た 後、最初のウィッティヒ反応で開環し、アルコール12を 76%の収率で得た。塩基促進脱離副生成物13の生成を抑 制するために、徹底的な最適化が必要であったことを強 調しておくべきである。 最適化された拡張性と再現性を 備えた条件は、0℃でトルエン中の過剰量のメチル(トリ フェニルホスホニウム) 臭化物から生成したイリドの懸濁 液に6aをゆっくりと制御添加し、その後室温まで昇温す るというものである(詳細は補足情報の表S1およびS2を 参照)。 8 1.A (5mol.%), NO2 P-Nitrophenol (10 mol. %) THF, 15°C, 4 days 2. NaBH4, MeOH, 0 °C, 1 h 89% (two steps), syn/anti 3:1 OPMB 9a *NO2 + HO. HO. OPMB syn-7a anti-7a 86% ee NO2 OPMB 90% ee MePPh3Br, KHMDS Toluene 20°C to rt, 16 h NaNO2 AcOH DMF, 40°C, 16h 1.DBU (20mol.%.) HO THF, r.t., 16 h 2. DIBAL-H Toluene, 87%, trans/cis 16:1 OPMB OPMB 11 -78 to -50°C, 30 min 6a 97% (two steps) HO. HO -OPMB 12 76% スキーム3 13 9% OPMB A Ph Ph OTMS

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TOEIC・英語 大学生・専門学校生・社会人

動詞の使い分けがわからないです😭

EXERCISE 20➤Looking at grammar. (Chart 5-6) Choose the correct completions. 1. The United States has have a population of around 325 million. an established and respected newspaper. a branch of mathematics. (2.) The New York Times: C:C/DC Caree 3. Statistics is/are 4. The statistics in that report on oil production :C:MKEKECRETKEY) incorrect.* 5. Fifty minutes is are the maximum length of time for the test. 6. Rabies (is) are an infectious and often fatal disease. The blind wants / want us to treat them the same way we treat everyone else. talking with people 8. French is are somewhat similar to Spanish, isn't it / aren't they? The French is are proud, independent people. 10. Does/Do the police have training in mental health issues? 1. Thirty dollars is an unreasonable price for that T-shirt. 12. Four hours of skiing provides / provide plenty of exercise. EXERCISE 21 ▸ Game. are (Chart 5-6) Work in teams. Choose the correct words (or numbers). Then complete the sentences with is or are. 1. The Scots /The Irish The English and Cambridge. 2. Statistics/Linguistics / Physics 3. Diabetes/Measles / Mumps 4. English / French / Afrikaans 5. People from Canada. called are famous for educational institutions like Oxford the study of the structure and nature of language. a blood-sugar illness. the official language of Namibia. Canadas/Canadians / Canadese. covered by water, but drinkable. 6. Approximately 60% / 70% / 80% of the earth only 1% / 10% / 20% of the earth's water 7. 312 x .5+ 100 227/275/256. 8. The United Arab Emirates/The Netherlands/The Philippines Hemisphere (i.e., north of the equator). in the Northern 9. Fish/Whales / Cattle not mammals. 10. Five hundred thousand + five hundred thousand ten hundred / one million / one billion. 11. Macy's/Harrods / Hudson's Bay a department store that began in London. *Statistics is singular when it refers to a field of study (e.g., Statistics is an interesting field of study.). When it refers to particular numbers, it is used as a count noun: singular one statistic (no final -s); plural = two statistics. For example, This

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第二外国語 大学生・専門学校生・社会人

空欄の解答を教えて下さい。

Friend I 定冠詞を入れよう。 Das ist mein Freund. Mein Freund ist Sänger. 1) Das ist das Haus 2) Die Hunde gefallen 訪問する singer 家 Freundes. 3) Ich besuche diesen Sommer 4格とる Freund. Freund. ※ diesen Sommer: 今夏 II 冠詞類の必要な語尾変化を入れ、文を完成させよう。 兄弟 1) A: Haben Sie Geschwister? 単数の場合 中性 B: Nein, ich habe kein Geschwister. Und Sie? 兄弟 Sister サ A: Ich habe ein Bruder und ein Schwester. 写真中性名詞 Das ist ihr Foto. 3格をとる。 自転車 ~のものである 2) A: Gehört dieses Fahrrad dein B: Ja, das Fahrrad mein 修理する格 Vater? 壊れてる Vater_ist kaputt. Mein Vater repariert sein_ help 3) Peter schreibt jeden Tag sein aber er bekommt kein Fahrrad. 3格になる。 4格女性名詞 Freundin ein E-Mail, Ich helfe mein Vater. 書く 毎日 girl friend しかし彼は 得る 「答え Antwort. 性格 携帯電話 もしかするとなくなっている。 Thr Handy ist vielleicht weg. ※ jeden Tag: 毎日 中性格 be 次のカードを使って、 文を完成させよう。 冠詞や名詞の変化語尾を入れ させよう。 中性名詞 1) アンナは彼女の子供達に一冊の辞書をプレゼントします。 プレゼントす ein Wörterbuch schenken Anna ihr Kinder 2) 私達の父の故郷はブレーメンです。 unser Vater 女性名詞 d Heimat Bremen sein

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TOEIC・英語 大学生・専門学校生・社会人

青くしてある文の文構造と訳し方を教えていただきたいです🙇‍♀️ また、mainstream America の語順に違和感を感じていて、(American mainstream とした方が正しくない?と思ってしまいます、、)それも解説いただきたいです。

Neil Hello. This is 6 Minute English from BBC Learning English. I'm Neil. Georgie And I'm Georgie. Neil If I told you I'd been for a walk to see Big Ben and Buckingham Palace, you'd know straight away I was in London. Georgie But what if my walk went past cafes selling mozzarella and ricotta where I smelled freshly made cannolis and focaccia... Where would I be then? Neil Focaccia and mozzarella... you'd be in Italy, right? Georgie Yes, Italy, or 'Little Italy' to be exact - the neighbourhood in some cities where Italian communities settled and made their home. Neil These Italian arrivals opened shops and cafes selling food to their own communities. Soon dishes like spaghetti and meatballs attracted the attention of local people, and gradually Italian food became famous around the world. In this programme, we'll be taking a walk through two Little Italys, one in Argentina, the other in New York, and, as usual, we'll be learning some useful new vocabulary as well. But before that, I have a question for you, Georgie. According to a recent YouGov poll, which Italian food is most popular with British diners? Is it: a) pizza? b) lasagne? or c) garlic bread? Georgie I think it must be pizza. Neil Okay, Georgie, I'll reveal the answer at the end of the programme. One country Italians moved to was Argentina. In 1898, Giuseppe Banchero arrived in the neighbourhood of La Boca, the Little Italy of Buenos Aires, where many Italian immigrants started restaurants. Here, Hugo Banchero, grandson of Giuseppe, tells his story to Veronica Smink, reporter for BBC World Service programme, The Food Chain: Hugo Banchero Well, my grandfather came from Italy, from Genoa, from Liguria. He was born in the centre of Genoa and arrived here in 1898 at the age of seven and a half, and this pizzeria where we are was founded on March 28, 1972. We have been here for 91 years. Veronica Smink So what culinary traditions did they bring with them? Hugo Banchero Well, our culinary tradition is pizza, and we incorporated the faina from Genoa, which is a pizza with chickpea flour... Georgie In 1898, Giuseppe founded his pizzeria - a restaurant selling pizza. When a business is founded, it's established someone starts it, or sets it up. Neil Giuseppe brought the culinary traditions from his home in Liguria in northern Italy, including regional pizzas like faina and fugazzetta. The adjective culinary describes anything connected with cooking. Georgie But probably the best-known Little Italy in the world is an area of Manhattan's Lower East side in New York. Ninety percent of Italian immigrants who arrived in the US at the turn of the century came through this neighbourhood. Neil De Palos, one of the original shops selling Italian food in Little Italy, has been serving customers for 113 years. Here, Lou De Palo, co-owner and great-grandson of the original owner, Salvino, explains more about his family history to BBC World Service programme, The Food Chain: Lou De Palo 1925... when my grandmother, Concetta, and my grandfather, Luigi, got married, they open their own shop... it's the shop we continue today being the fourth generation working alongside my sister, Maria, my brother, Sal, and our children, the fifth generation. Our business has expanded; expanded to present the full food culture of the 20 regions of Italy. Little Italy is the stepping stone of the Italian immigrant. This is where many of the Italians first came through Ellis Island, and then settled here, and then eventually moved into mainstream America throughout the rest of the country. Georgie Lou De Palo is the fourth generation of his family to run the shop, and his children will be the fifth. Phrases like fourth or fifth generation describe the children of people whose parents immigrated to a particular country.

未解決 回答数: 1
TOEIC・英語 大学生・専門学校生・社会人

下線部(1)の文構造が分かりません。特に2行目の文構造が分かりません。強調のdoであることは分かりますが、その後のthat以降が関係詞?かすらも分からないので、誰か教えて下さい!

次の英文は1991年に出版された本からのもので、 研究分野としての「人工知 能」 (Artificial Intelligence) について述べています。 下線部(1)~(3)を日本語に訳 しなさい。 What is Artificial Intelligence (AI)? Just about the only characterization of Al that would meet with universal acceptance is that it involves trying to make machines do tasks which are normally seen as requiring intelligence. There are countless refinements of this characterization: what sort of machines we want to consider; how we decide what tasks require intelligence and so on. One of the most important questions concerns the reasons why we want to make machines do such tasks. AI has always been split between people who want to make machines do tasks that require intelligence because they want more useful machines, and people who want to do it because they see it as a way of exploring how humans do such tasks. We will call the two approaches the engineering approach and the cognitive-science respectively. (2) (1) approach The techniques required for the two approaches are not always very different. For many of the tasks that engineering AI wants solutions to, the only systems we know about that can perform them are humans), so that, at least initially, the obvious way to design solutions is to try to mimic what we know about humans. For many of the tasks that cognitive-science Al wants solutions to, the evidence on how humans do them is too hard to interpret to enable us to construct computational models, so the only approach is to try to design solutions from scratch" and then see how well they fit what we know about humans. The main visible difference between the two approaches is in (3) their criteria for success; an engineer would be delighted to have create something that outperformed a person; a cognitive scientist would regard it as a failure. -1- M7 (492-61

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