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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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TOEIC・英語 大学生・専門学校生・社会人

わからないので答えを教えてもらいたいです。

英語 Amy: Hey Jake, I was thinking about online shopping this weekend. Do you shop online often? Jake: Yeah, I do it quite a bit. It's so ( house and you can ( ) almost anything online. That's true. I love the convenience, too, especially with a busy schedule. But I've heard there are some downsides to it. What do you think? Well, one obvious downside is not being able to ( ) or try the product before buying. Sometimes, what you see on the website isn't exactly what you get. Amy: Yeah, that's a good point. I've had a couple of instances where the color or size was ) from what I expected. ( Another thing is the shipping time. Even with express shipping, you might have to ( ) a few days for your stuff to arrive. It's not great if you need Amy: Jake: Jake: Amy: Amy: Jake: Jake: Jake: something urgently. True, waiting can be frustrating. But what about the ( that sometimes the prices are higher online. It depends. I've found some great deals online, especially during sales. But you're right; in some cases, the prices can be a bit inflated, and you might end up paying more than if you bought it in-store. Amy: And returns can be a hassle, too. I had to return a shirt once, and the process took forever. It's not as easy as just going to a store and returning it on the spot. Yeah, returns can be a pain. Also, there's the whole security issue. You must be careful about where you're buying from to avoid scams or stealing your ( ). Amy: Oh, definitely. I always make sure the website is secure before entering any payment details. 日本語 L ), you know? No need to leave the On the bright side, online ( ) can be super helpful. I always check them before making a purchase. It gives you an idea of the product's quality and whether it's worth the money. Amy: That's a good point. I do the same. It's like having the opinions of a bunch of friends who've already ( ) the product. Jake: Exactly. So, while there are some drawbacks, I think the ( ) of online shopping, like the convenience and variety, outweigh the ( ) for me. Yeah, I agree. It's all about finding a balance and being cautious about where and what you're buying. )? I've heard

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