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化学 大学生・専門学校生・社会人

有機化学の質問です。以下の問題の解答解説をお願いします。 問題1. 3-メチル-1-ブテン (3-methyl-1-butene) を原料に、①HBrを用いて臭素化した場合、②HBrとラジカル開始剤である過酸化ベンゾイルを用いて臭素化した場合に何が生成するか。中間体と主生成... 続きを読む

問題 1. 3-メチル-1-ブテン (3-methyl-1-butene) を原料に、 ① HBr を用いて臭素化した場合、②HBr とラジカル開始剤である過酸化ベンゾイルを用いて臭素化した場合に何が生成するか。 中間体と主 生成物の構造、主生成物の名称 (日本語でも英語でも良い)をそれぞれ答えなさい。 (1) (2) 3-methyl-1-butene 3-methyl-1-butene (2) BzOOBz: 過酸化ベンゾイル (7) (8) 名称 HBr HBr BzOOBz 原料 1-methyl-1-cyclopentene NBS BzOOBz カチオン中間体 主生成物 問題2. ① ある原料にN-ブロモスクシンイミドと過酸化ベンゾイルを用いて臭素化したところ、 (1-ブロモエチル)ベンゼン [(1-bromoethyl)benzene] が生成した。 原料とその名称(日本語でも英 語でも良い)をそれぞれ答えなさい。 ②また、 1-メチル-1-シクロペンテン (1-methyl-1- cyclopentene) BH を作用させたところ、 分子式 C6H13Bの中間体が得られ、さらにH2O2 を作用 させたところ、主生成物としてアルコール体が得られた。 中間体、主生成物の相対立体化学を含 めた化学構造をそれぞれ答えなさい。 なお、 立体化学については破線‐くさび形表記で示せ。 Br 1) BH3 (4) ラジカル中間体 Br (9) (3) 名称 (6) 名称 (1-bromoethyl)benzene 主生成物 分子式: C6H13B 中間体 (5) 主生成物 NBS: N-ブロモスクシンイミド O O BzOOBz: 過酸化ベンゾイル 2) H2O2 (10) 主生成物

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TOEIC・英語 大学生・専門学校生・社会人

答え合わせの為、答えを教えて頂きたいです。 よろしくお願いします。ビジネス英語です。

Working with words 1 Complete the sentences with the words in bold. Change the form of the word in bold or add another word to it. supply 1 It's important to build good relationships with different suppliers. 2 Our supply chain begins with the manufacturer in India and ends in our UK shops. is much higher but it's transport 3 The cost of air faster. show 4 Customers from all over Europe visit our in Paris and Milan. invent 5 Every item in our photographic records of each of them. middle 6 The problem with using is that it adds to the final cost of products because we have to add on their fee. is unique, so we keep ship 7 We have a large. track 8 We use barcodes to stock coming in and out of the warehouse. made 9 All our pots are _, which makes them expensive, but our target customer doesn't want anything mass-produced. original 10 The arriving in three days. of the of the products is printed on the bottom of the box. 2 Underline the correct words in italics to complete the sentences. 1 The book is currently out of stock, but it is on / out of order, so we'll have it soon. 2 We need to stock up on / run out of headed paper. Could you put an order in? 3 I ran low on/out of ink, so I couldn't print out the report. 4 We can keep track of/ on track our order by satellite. 5 Let's stop at the next service station. We are running low/out on petrol. Business 1 Complete the phone call between Virginie, a customer, and Kevin, a call handler. Put the words in italics in the correct order. Kevin Good afternoon, you're speaking to Kevin. How can I help you? Virginie Hello, I am up/chasing/an/order chasing up an order I placed three weeks ago. Kevin account /take/I/your/details / Can please? 2 Virginie Yes. The account number is 572638. Kevin OK. If you bear with me a moment, I'll into / look/it 3 Let me see. Well, my /to / information / according it is still on order. 4 Virginie I really need to know happened /to/has/it/ what 5 Could check/me/you/it/for/out 6 ? Kevin Certainly. I'll back/you/to/hour / within/get/ the 7 Virginie Thank you. 2 Kevin calls Virginie back. Complete their conversation with the phrases from the list. put the order straight through asap charge it to was dispatched on check it out as quick as we can must have gone wrong Kevin Hello, this is Kevin from DYK calling. I've got some information about your order. Virginie Oh, thanks for calling back. So, what's happened to it? Kevin Well, we put the order straight through to the warehouse, and it 2_ the 25th. Virginie But I haven't received it yet. Kevin I'm sorry about that. Can you confirm the delivery address? Virginie We wanted it delivered to our Brussels office. Kevin Oh, something 3 It looks like it might have gone to your Paris office instead. I'll 4 straightaway. Virginie I've already been waiting three weeks. Could you just send it again 5 ? Kevin OK, no problem. We'll resend it Virginie Thank you. And please not the Paris one. the Brussels account,

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TOEIC・英語 大学生・専門学校生・社会人

自分の回答があっているか不安なので、4第答えて頂きたいです。 自分の回答はこちらには見にくくなってしまうため書いていません。

Working with words 1 Complete the review of a hotel. Use the answers to complete the puzzle and find the European city where the hotel is located. HOTEL REVIEWS This first-class hotel and conference centre welcomes guests from all over the world. Its 1 facilities are second to none. There are 300 en-suite rooms and five apartment suites. For business guests, it has ten meetings rooms, two of which are big enough to be used as halls. 2 The hotel can also organize events such as guided 3 around the town centre for conference 4 and hotel guests who enjoy a bit of 5 For food-lovers, the four-star restaurant serves regional 6 every evening. All in all, this is a top-class for business and for pleasure. 7 6 1 A fa 0 il i t 1 e S 2 Replace the words in italics (1-8) with the phrases from the list. Add a pronoun if necessary. you hotel? look around meet up with show someone around 3 freshen up eat out pick someone up check in drop someone off Pedro It's difficult to park here. Can I stop and leave drop you off in front of the 1 Sabrina Sure, I'll register 2 and then I'd like to have a wash, and change my clothes 3 Pedro If you like, tonight I can give you a tour of 4 the old city. We could by eat in a restaurant 5 the port. Sabrina That sounds great! I'd rather walk about and See 6 the city than stay in my hotel room. Pedro I'll collect you 7 8 8.30 p.m. We'll see Alberto and Maite in the main square. at Business communication 1 Put the words in the correct order to make expressions. 1 meet person / it's / nice / to / you / in It's nice to meet you in person 2 have / did / finding / you/ any / trouble / us? 3 worry / signing / don't / about / in 4 through / programme / I'll / run / today's 5 this my / come / way / to / office 6 need building / you'll / this / enter / badge/ the / to 7 reception / sure / make / in / at / you / sign 2 Raymond Roberts has an appointment with Janet Rose. He has just arrived at HBG premises. Complete their conversation with the phrases from the list. let me take your bag can I get you a drink Welcome to HBG publishing I thought you could catch up again how was your journey You'll need this Make sure you 1 Raymond Good morning, I'm here to see Janet Rose. Janet Hello, I'm Janet. ¹ Welcome to HBG publishing. Raymond It's nice to meet you in person. Janet Likewise. So, 2 Raymond Well, there were traffic jams on the motorway and I got a little bit lost in the industrial park. Janet Don't worry. That happens to everyone. Anyway, 3 - I'll store it in my office. Raymond I'll hang on to it if you don't mind. It's got all my stuff in it. Janet Well, if you change your mind just tell me. And 4 Raymond Thanks. I'll have a cup of tea, please. Janet Sure, I'll just get that for you in a second. First of all, I'll run through the schedule. 5 start by meeting Karen Rankin this morning and then we'll 6 at lunchtime. Raymond OK. And will I see Malcolm Briscoe? Janet Yes, in fact he's joining us for lunch. One other thing. security pass. at all times. 7 It's your 8 wear it

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