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Chelation effect change two entropy
1. The entropy of the conformation of molecule.bidentate ligand is with more constraint than monodentate ligand.but it’s relatively small
2.the entropy of freely moving molecule.Bidentate ligand forms a more complete structure with less interaction with other entity.Therein,the increase number of free moving molecules.
The above result is the the increasing entropy of chelator than monodentate ligand. In the opinion of free energy,increasing entropy means the the product are more stable.

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