自然科學
大學
求分析化學解答
Derive the expression of concentration-based equilibrium constant (K') in terms of
thermodynamic equilibrium constant (K) and the activity coefficients (y;) of the participating
species for the dissociation reaction in a supersaturated aqueous solution of silver arsenate,
AgzAsO4(s).
For the titration of 50.0 mL of 0.00500 M Ni2+ with 0.0100 M EDTA in a solution buffered
to a constant pH of 10.0. Express (NiY2-), Ct, and K'Niy2- in terms of (Ni) after the addition
of 30.0 mL of EDTA.
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