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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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英語 中学生

いの答えと考え方を教えてください。

5 10 15 20 25 30 The Olympics were held in Tokyo in 1964. A few years ago before the Olympics, Japan had a big problem. It was a problem of communication. Many foreign people didn't visit Japan, and we had only, Japanese signs. For example, words like "i" or "" were on toilet doors. These signs were not understood by many foreign people. Japanese people at that time needed to make signs in many different languages for foreign people. But when they put many words on one sign, the "letters became too small. They could not easily read the sign. They had to think of ) signs for foreign people. Mr. Masaru Katsumi, a leader of a design team for the Olympics, had a great idea. everyone /to/ was easy / thought / understand he forit pictures. He wanted to make picture signs. These signs are called *pictograms and are used in many places now. Picture 1 Picture 2 Picture 3 Look at these pictures. Picture 1 shows a shower. Picture 2, shows a toilet. Picture 3 shows a restaurant. Foreign people can easily understand what each picture shows. They had to make pictograms which everyone could understand without any trouble. When they started to make them, one of the pictograms was a shower. Many Japanese people didn't know about showers at that time and didn't have one at home. One of the designers didn't even know the word "shower." One officer had to explain how to use it with a photo of a shower. The designer made the pictograms through the officer's words. With a lot of trouble and hard work, twelve designers needed three months and made pictograms for the Olympics. When the last pictogram was finished, Mr. Katsumi said to all the designers, "You did a great job, but this work is not for us. We did it for all Japanese people. Please write your names on this paper." The paper said that they'd like to give up the *copyright to the pictograms. They wrote their names on the paper. They gave up the copyright. One of the designers said, "Mr. Katsumi hopes that many people in many places will use the pictograms in the future. Money from the copyright is not important to Mr. Katsumi. He is proud that he is one of the members who worked for the Tokyo Olympics." In 2020, we are going to have the Olympics in Tokyo. Our life will change a lot. What kinds of new signs or pictograms will we see around us? (E) letter pictogram ピクトグラム(絵文字) designer www. デザイナー officer 役人 copyright 著作権

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