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自然科學 大學

想問3-9的a跟c

Problems 3-1. Explain the difference between *(a) random and systematic error. (b) constant and proportional error. *(c) absolute and relative error. (d) mean and median. *3-2. Suggest two sources of systematic error and two sources of random error in measuring the length of a 3-m table with a 1-m metal rule. 3-3. Name three types of systematic errors. *3-4. Describe at least three systematic errors that might occur while weighing a solid on an analytical balance. *3-5. Describe at least three ways in which a systematic error might occur while using a pipet to transfer a known volume of liquid. 3-6. Describe how systematic method errors may be detected. *3-7. What kind of systematic errors are detected by varying the sample size? 3-8. A method of analysis yields masses of gold that are low by 0.4 mg. Calculate the percent relative error caused by this result if the mass of gold in the sample is (a) 500 mg. (b) 250 mg. V(c) 125 mg. (d) 60 mg. 3-9. The method described in Problem 3-8 is to be used for the analysis of ores that assay about 1.2% gold. What minimum sample mass should be taken if the relative érror resulting from a 0.4-mg loss is not to exceed *(a) -0.1%? (b) -0.4%? (c) -0.8%? (d) - 1.1%? 3-10. The color change of a chemical indicator requires an overtitration of 0.03 mL. Calculate the error if the total volume of titrant is percent relative (a) 50.00 mL. (c) 25.0 mL. 3-11. A loss of 0.4 mg of Zn occurs in the course of an percent relative analysis for that element. Calculate the error due to this loss if the mass of Zn in the sample is *(b) 10.0 mL. (d) 30.0 mL. 190 (c) 188 (d) 4.52 x 103 4.63 x 103 4.53 x 10 ³ √6 *(a) 30 mg. (b) 100 mg. *(c) 300 mg. (d) 500 mg. 3-12. Find the mean and median of each of the following sets of data. Determine the deviation from the mean for each data point within the sets, and find the mean devi- Vation for each set. Use a spreadsheet if it is convenient. *(a) 0.0110 0.0105 (b) 24.53 0.0104 24.68 24.81 24.77 39.61 862 (f) 850 MA 3-13. Challenge Problem: Richards and W the molar mass of lithium and colle data. 24.73 Experiment 1 2 3 4 5 6 194 447 X 10 7 448 X 107 4.58 X 10 (a) Find the mean molar t workers. (b) Find the median molar ma (c) Assuming that the cam molar mass of lithium is the absolute ertor and of the mean value demi Willard. (d) Find in the chemical ues for the molar mus since 1910, and ag a table or spreadshera 1817 given in the a Richards and Willd. Com mass versus year to la of lithium has chang Suggest possible abruptly about 18 ant de (e) The incredibly deals Richards and W that major changes will occur. Disc calculation in pat (f) What factors ha since 1910? (g) How would you mass? 6See Chapter 2 of Applications of Microsoft Excel in Analytical Chemistry, 4th ed., for information about statistical 7T. W. Richards and H. H. Willard, J. Am. Chem. Soc., 1910, 32, 4, DOI: 10.1021/ja01919a002. built-in statistical functions. "Answers are provided at the end of the book for questions and problems marked with an asterisk The I of ₂ or inc rce of able vas error c often in individu ate resul data in rtainties. dimensio andom e analysts The result

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自然科學 大學

大一普化 5.36求解

5.38 9389 信4 5,42 sphere (about 30 Where the temperatu lbove the surface of Earth), >and presSure are 一235C : h gd 交 and 3.00 XX 10 atm, respectively. Calculate the final Volume of the balloon. The temperature ot 2.5 L of a gas initially at SUN increased to 2507”C at constant volume. Calculate the final pressure of the gas in atm. The pressure of 6.0 L of an ideal gas in aflexible contalner 1S decreased to one-third of its original presSure, and 1ts absolute temperature 1s decreased by one-half. What 1s the flnal volume of the gas? A gas evolved during the tfermentation of glucose (wine making) has a volume of 0.78 L when mea- sured at 20.1?C and 1.00 atm. What was the volume of this gas at the fermentation temperature of 36.5 C and 1.00 atm presSure? An ideal gas originally at 0.85 atm and 66”C was allowed to expand until its final Volume, preSSure, and temperature were 94 mL, 0.60 atm, and 45 C, respectively. What was its initial volume? The volume of a gas at STP is 488 mL. Calculate 1ts volume at 22.5 atm and 1507C. A gas at 772 mmHg and 35.0”C Qceuples a Volume of 6.85工. Calculate its volume at STEP. Dry ice is solid carbon dioxide. A 0.050-g sample ot dry ice js placed in an evacuated 4.6-L vessel at 30。C. Caleulate the pressure inside the VesSel after all the dry ice has been conVerted to CO gasS, Avolume of 0.280Lofagas at STP weighs 0.400 g. Calculate the molar mass Of the gas. Aquantity of gas Weighing 7.10g at741tor and 445C oeeupies a volume of 5.40L. What is its molar mass? Si人2 5.93 5.54 Dalt 和Ae0U76 5 5.56

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