ページ1:

aA+bB CC+dD
CD]
rate = -1 A-LATE] = []=[]
-ast
= KTAJTBJa) 反應級权:由experiment 決定
first order reaction:
ATAJ
dt
KTAJ
-
|=
In [A]t-In [A] = kt
second-order reaction:
-da] KLAJ
dt
LAJE
[A]
S] = √,²k dt
- TAJE + TAD. = -kt
InTAJt= t + In [A]
⇒ CATE = kt + LA]o
*half-life t
[A] += [A]
In = -kt±
0.693
-0.693=-kt₁ = k #
Arrhenius equation:
k= Ae, R= 3.314 J/mol.k
↓ ↓
orientation energy